Phase transitions in alumina films during post-sparking anodising of Al alloys
نویسندگان
چکیده
Formation of the high-temperature ?-Al2O3 phase during Plasma Electrolytic Oxidation aluminium at ambient bulk temperatures has been previously attributed to local microdischarge events providing multiple melting-solidification cycles in micro-volumes surface oxide layer. In this work, it is demonstrated that ? can be formed even if fully suppressed under specific processing conditions. Oxide layers produced post-sparking anodising mode were studied by FIB, TEM, EBSD, EDS and GDOES techniques reveal microstructural chemical evolutions accompany ? alumina transition. Our results provide strong evidence form spontaneously regions with appropriate temperature, grain size impurity distributions ?-Al2O3 matrix allow sufficient mobility ?/? boundaries. Ionic migration within hydrothermal dissolution/precipitation associated microporous network facilitate species boundaries critical temperature for activation ??? transition reduced. Overall, suggested layer growth considered terms a relatively simple Plug Flow Reactor model. This help predict kinetics depending on key parameters such as current density frequency pulse polarisation, thus enabling optimum control coating microstructure application requirements.
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ژورنال
عنوان ژورنال: Acta Materialia
سال: 2023
ISSN: ['1873-2453', '1359-6454']
DOI: https://doi.org/10.1016/j.actamat.2022.118587